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dc.contributor.authorNita, Rafaela
dc.contributor.authorDeschamps, Jeffery R.
dc.contributor.authorTrammell, Scott A.
dc.contributor.authorKnight, D. Andrew
dc.identifier.citationNita, R., Deschamps, J.R., Trammell, S.A., Knight, D.A. Crystal structure of catena-poly[[chlorido(4,4'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II)]-μ-chlorido] (2015) Acta Crystallographica Section E: Crystallographic Communications, 71, pp. 624-627.en_US
dc.descriptionCopper bipyridine complex, Crystal structure, Dehydration, Hydrogen bondingen_US
dc.description.abstractThe title compound, [CuCl2(C12H12N2)]n, was obtained via a DMSO-mediated dehydration of Cu(4,4'-dimethyl-2,2'-bipyridine)copper(II)·0.25H2O. The central CuII atom is coordinated in a distorted trigonal-bipyramidal geometry by two N atoms of a chelating 4,4'-dimethyl-2,2'-bipyridine ligand [average Cu-N = 2.03 (3) Å] and three Cl atoms, one terminal with a short Cu-Cl bond of 2.2506 (10) Å, and two symmetry-equivalent and bridging bonds. The bridging Cl atom links the CuII ions into chains parallel to [001] via one medium and one long Cu-Cl bond [2.3320 (10) and 2.5623 (9) Å]. The structure displays both inter- and intramolecular C-H⋯Cl hydrogen bonding.en_US
dc.rights© 2015 The Authorsen_US
dc.titleCrystal structure of catena-poly[[chlorido(4,4'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II)]-μ-chlorido]en_US

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